SemOpenAlex |

SemOpenAlex

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045441360> ?p ?o ?g. }

Showing items 1 to 100 of ±114 with 100 items per page.

W2045441360 endingPage "1668" @default.
W2045441360 startingPage "1662" @default.
W2045441360 abstract "The hydroxo complexes [NBu4]2[{M(C6F5)2(μ-OH)}2] (M = Pd, Pt) react with phenols ROH (1:2 molar ratio) to give the bis(μ-aryloxo) complexes [NBu4]2[{M(C6F5)2(μ-OR)}2] (M = Pd, Pt; R = C6H5, p-MeC6H4, p-NO2C6H4, C6F5). The reaction of bis(μ-aryloxo) complexes with PPh3 (1:2 molar ratio) gives the aryloxo monomer complexes [NBu4][M(C6F5)2(OR)(PPh3)] (M = Pd, Pt; R = p-NO2C6H4, C6F5). The platinum monocarbonyl complexes [NBu4][Pt(C6F5)2(OR)(CO)] (R = p-NO2C6H4, C6F5) have also been prepared by reaction of the corresponding bis(μ-aryloxo) complexes with carbon monoxide at room temperature and normal pressure. [NBu4][Pd(C6F5)3(CO)] is isolated in low yield from the reaction of [NBu4]2[Pd(C6F5)2(μ-OC6H4NO2-p)] with CO in the presence of water. The identity of the isolated complexes has been established by partial elemental analyses, conductance measurements, and spectroscopic (IR, 1H, 19F, 31P) methods. A single-crystal diffraction study of [NBu4][Pt(C6F5)2(OC6H4NO2-p)(CO)] showed that coordination about platinum was approximately square-planar with the aryl rings tilted to avoid steric crowding." @default.
W2045441360 created "2016-06-24" @default.
W2045441360 creator A5000195518 @default.
W2045441360 creator A5012497133 @default.
W2045441360 creator A5026262437 @default.
W2045441360 creator A5030953437 @default.
W2045441360 creator A5081286391 @default.
W2045441360 date "1996-03-19" @default.
W2045441360 modified "2023-10-17" @default.
W2045441360 title "Synthesis and Reactivity of Binuclear Bis(μ-aryloxo) Complexes of Palladium and Platinum. Crystal Structure of [NBu4][Pt(C6F5)2(OC6H4NO2-p)(CO)]" @default.
W2045441360 cites W1847032888 @default.
W2045441360 cites W1969224698 @default.
W2045441360 cites W1971428024 @default.
W2045441360 cites W1972580049 @default.
W2045441360 cites W1976215358 @default.
W2045441360 cites W1978103182 @default.
W2045441360 cites W1982013621 @default.
W2045441360 cites W1985857706 @default.
W2045441360 cites W1994655214 @default.
W2045441360 cites W1998722626 @default.
W2045441360 cites W1999102466 @default.
W2045441360 cites W2006500797 @default.
W2045441360 cites W2009503332 @default.
W2045441360 cites W2014131025 @default.
W2045441360 cites W2014441650 @default.
W2045441360 cites W2019270500 @default.
W2045441360 cites W2020548209 @default.
W2045441360 cites W2021155630 @default.
W2045441360 cites W2021376891 @default.
W2045441360 cites W2026051853 @default.
W2045441360 cites W2027266092 @default.
W2045441360 cites W2036867671 @default.
W2045441360 cites W2039618529 @default.
W2045441360 cites W2047166097 @default.
W2045441360 cites W2055087571 @default.
W2045441360 cites W2061095827 @default.
W2045441360 cites W2073511802 @default.
W2045441360 cites W2077975636 @default.
W2045441360 cites W2081997404 @default.
W2045441360 cites W2083072588 @default.
W2045441360 cites W2089655596 @default.
W2045441360 cites W2089862541 @default.
W2045441360 cites W2114388532 @default.
W2045441360 cites W2168939510 @default.
W2045441360 doi "https://doi.org/10.1021/om950409a" @default.
W2045441360 hasPublicationYear "1996" @default.
W2045441360 type Work @default.
W2045441360 sameAs 2045441360 @default.
W2045441360 citedByCount "25" @default.
W2045441360 crossrefType "journal-article" @default.
W2045441360 hasAuthorship W2045441360A5000195518 @default.
W2045441360 hasAuthorship W2045441360A5012497133 @default.
W2045441360 hasAuthorship W2045441360A5026262437 @default.
W2045441360 hasAuthorship W2045441360A5030953437 @default.
W2045441360 hasAuthorship W2045441360A5081286391 @default.
W2045441360 hasConcept C115624301 @default.
W2045441360 hasConcept C142724271 @default.
W2045441360 hasConcept C155647269 @default.
W2045441360 hasConcept C161790260 @default.
W2045441360 hasConcept C178790620 @default.
W2045441360 hasConcept C185592680 @default.
W2045441360 hasConcept C201194858 @default.
W2045441360 hasConcept C204787440 @default.
W2045441360 hasConcept C2776910235 @default.
W2045441360 hasConcept C2780263894 @default.
W2045441360 hasConcept C2781076698 @default.
W2045441360 hasConcept C2994067411 @default.
W2045441360 hasConcept C502130503 @default.
W2045441360 hasConcept C512735826 @default.
W2045441360 hasConcept C518104683 @default.
W2045441360 hasConcept C71240020 @default.
W2045441360 hasConcept C71924100 @default.
W2045441360 hasConcept C73922627 @default.
W2045441360 hasConcept C8010536 @default.
W2045441360 hasConceptScore W2045441360C115624301 @default.
W2045441360 hasConceptScore W2045441360C142724271 @default.
W2045441360 hasConceptScore W2045441360C155647269 @default.
W2045441360 hasConceptScore W2045441360C161790260 @default.
W2045441360 hasConceptScore W2045441360C178790620 @default.
W2045441360 hasConceptScore W2045441360C185592680 @default.
W2045441360 hasConceptScore W2045441360C201194858 @default.
W2045441360 hasConceptScore W2045441360C204787440 @default.
W2045441360 hasConceptScore W2045441360C2776910235 @default.
W2045441360 hasConceptScore W2045441360C2780263894 @default.
W2045441360 hasConceptScore W2045441360C2781076698 @default.
W2045441360 hasConceptScore W2045441360C2994067411 @default.
W2045441360 hasConceptScore W2045441360C502130503 @default.
W2045441360 hasConceptScore W2045441360C512735826 @default.
W2045441360 hasConceptScore W2045441360C518104683 @default.
W2045441360 hasConceptScore W2045441360C71240020 @default.
W2045441360 hasConceptScore W2045441360C71924100 @default.
W2045441360 hasConceptScore W2045441360C73922627 @default.
W2045441360 hasConceptScore W2045441360C8010536 @default.
W2045441360 hasIssue "6" @default.
W2045441360 hasLocation W20454413601 @default.
W2045441360 hasOpenAccess W2045441360 @default.
W2045441360 hasPrimaryLocation W20454413601 @default.
W2045441360 hasRelatedWork W1558163028 @default.