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- W2045448934 abstract "The endo,endo-2,3-dibromo-7-oxanorborneno[2,3-c]succinimide (1) undergoes complete inversion upon hydrogenolysis of the bromine substituents to form (5)(Zn/Ag couple in THF) or (26)(H2, Pd/C). The highly reactive dienophile, N-methyl 7-oxanorbornadieno[2,3-c]maleimide (3) is shown to be a transient intermediates in the Zn/Ag couple experiments by trapping with furan. Deuterium labelling experiments have been used to help elucidate the mechanism of these reactions." @default.
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- W2045448934 date "1994-04-01" @default.
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- W2045448934 title "Evidence for an olefinic intermediate in the configurational inversion accompanying hydrogenolysis of a 7-oxanorbornyl vicinal dibromide" @default.
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- W2045448934 doi "https://doi.org/10.1016/0040-4039(94)85227-8" @default.
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