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- W2045449563 abstract "The i.r. spectra of titanium tetrachloride and germanium tetrachloride in argon matrices have been recorded in the region of the ν3(F2) fundamental. The same has been done for the samples 48TiCl4, Ti35Cl4, 74GeCl4 and Ge35Cl4. In this manner assignments could be made with a high order of certainty. The same region has been studied for the pure isotopic species 48Ti35Cl4 and 48Ti35Cl4, in the gas phase. Similarly, the spectra of the isotopically pure species of germanium tetrachloride, 74Ge35Cl4 and 74Ge37Cl4, and of the normal compound have been recorded in the gas phase for both the F2 modes for which Coriolis coupling constants were calculated from the i.r. band contours. Using six independent isotopic shifts for titanium tetrachloride, four ζ-values and three isotopic shifts for germanium tetrachloride as additional data, force constants have been calculated. The force field for both molecules have much smaller error limits when compared with those previously reported." @default.
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- W2045449563 date "1976-01-01" @default.
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- W2045449563 title "Combination of the matrix isolation and the isotropic substitution techniques: Vibrational spectra and molecular constants of titanium tetrachloride and germanium tetrachloride" @default.
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- W2045449563 doi "https://doi.org/10.1016/0584-8539(76)80160-2" @default.
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