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• W2045453312 endingPage "11158" @default.
• W2045453312 startingPage "11146" @default.
• W2045453312 abstract "(Eta6-naphthalene)Mn(CO)(3)(+) is reduced reversibly by two electrons in CH(2)Cl(2) to afford (eta4-naphthalene)Mn(CO)(3)(-). The chemical and electrochemical reductions of this and analogous complexes containing polycyclic aromatic hydrocarbons (PAH) coordinated to Mn(CO)(3)(+) indicate that the second electron addition is thermodynamically easier but kinetically slower than the first addition. Density functional theory calculations suggest that most of the bending or folding of the naphthalene ring that accompanies the eta6 --> eta4 hapticity change occurs when the second electron is added. As an alternative to further reduction, the 19-electron radicals (eta6-PAH)Mn(CO)(3) can undergo catalytic CO substitution when phosphite nucleophiles are present. Chemical reduction of (eta6-naphthalene)Mn(CO)(3)(+) and analogues with one equivalent of cobaltocene affords a syn-facial bimetallic complex (eta4,eta6-naphthalene)Mn(2)(CO)(5), which contains a Mn-Mn bond. Catalytic oxidative activation under CO reversibly converts this complex to the zwitterionic syn-facial bimetallic (eta4,eta6-naphthalene)Mn(2)(CO)(6), in which the Mn-Mn bond is cleaved and the naphthalene ring is bent by 45 degrees . Controlled reduction experiments at variable temperatures indicate that the bimetallic (eta4,eta6-naphthalene)Mn(2)(CO)(5) originates from the reaction of (eta4-naphthalene)Mn(CO)(3)(-) acting as a nucleophile to displace the arene from (eta6-naphthalene)Mn(CO)(3)(+). Heteronuclear syn-facial and anti-facial bimetallics are formed by the reduction of mixtures of (eta6-naphthalene)Mn(CO)(3)(+) and other complexes containing a fused polycyclic ring, e.g., (eta5-indenyl)Fe(CO)(3)(+) and (eta6-naphthalene)FeCp(+). The great ease with which naphthalene-type manganese tricarbonyl complexes undergo an eta6 --> eta4 hapticity change is the basis for the formation of both the homo- and heteronuclear bimetallics, for the observed two-electron reduction, and for the far greater reactivity of (eta6-PAH)Mn(CO)(3)(+) complexes in comparison to monocyclic arene analogues." @default.
• W2045453312 created "2016-06-24" @default.
• W2045453312 creator A5009042832 @default.
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• W2045453312 creator A5065440051 @default.
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• W2045453312 creator A5079321243 @default.
• W2045453312 date "2005-07-19" @default.
• W2045453312 modified "2023-10-14" @default.
• W2045453312 title "Chemical and Electrochemical Reduction of Polyarene Manganese Tricarbonyl Cations: Hapticity Changes and Generation of <i>Syn</i>- and <i>Anti</i>-Facial Bimetallic η⁴,η⁶-Naphthalene Complexes" @default.
• W2045453312 cites W1559064942 @default.
• W2045453312 cites W1964358578 @default.
• W2045453312 cites W1964583937 @default.
• W2045453312 cites W1965129522 @default.
• W2045453312 cites W1967468228 @default.
• W2045453312 cites W1970568572 @default.
• W2045453312 cites W1973137947 @default.
• W2045453312 cites W1974235888 @default.
• W2045453312 cites W1975459660 @default.
• W2045453312 cites W1977121325 @default.
• W2045453312 cites W1979727133 @default.
• W2045453312 cites W1980345483 @default.
• W2045453312 cites W1981647051 @default.
• W2045453312 cites W1982302870 @default.
• W2045453312 cites W1986293390 @default.
• W2045453312 cites W1986953916 @default.
• W2045453312 cites W1987517363 @default.
• W2045453312 cites W1991176554 @default.
• W2045453312 cites W1992197023 @default.
• W2045453312 cites W1992330513 @default.
• W2045453312 cites W1996213290 @default.
• W2045453312 cites W1997015853 @default.
• W2045453312 cites W1997900159 @default.
• W2045453312 cites W2005474298 @default.
• W2045453312 cites W2005514964 @default.
• W2045453312 cites W2008150814 @default.
• W2045453312 cites W2008241604 @default.
• W2045453312 cites W2009954501 @default.
• W2045453312 cites W2010351442 @default.
• W2045453312 cites W2011865693 @default.
• W2045453312 cites W2013225481 @default.
• W2045453312 cites W2013578681 @default.
• W2045453312 cites W2013801427 @default.
• W2045453312 cites W2016062868 @default.
• W2045453312 cites W2017929292 @default.
• W2045453312 cites W2017943904 @default.
• W2045453312 cites W2019064975 @default.
• W2045453312 cites W2019635206 @default.
• W2045453312 cites W2023271753 @default.
• W2045453312 cites W2024709152 @default.
• W2045453312 cites W2028902050 @default.
• W2045453312 cites W2028912460 @default.
• W2045453312 cites W2030285095 @default.
• W2045453312 cites W2031616080 @default.
• W2045453312 cites W2038310780 @default.
• W2045453312 cites W2039744940 @default.
• W2045453312 cites W2041594924 @default.
• W2045453312 cites W2041765362 @default.
• W2045453312 cites W2044490585 @default.
• W2045453312 cites W2044550215 @default.
• W2045453312 cites W2044826218 @default.
• W2045453312 cites W2044841404 @default.
• W2045453312 cites W2045469049 @default.
• W2045453312 cites W2046409117 @default.
• W2045453312 cites W2046742729 @default.
• W2045453312 cites W2058665938 @default.
• W2045453312 cites W2058806136 @default.
• W2045453312 cites W2059220513 @default.
• W2045453312 cites W2060022567 @default.
• W2045453312 cites W2062679610 @default.
• W2045453312 cites W2063151161 @default.
• W2045453312 cites W2064037995 @default.
• W2045453312 cites W2065656814 @default.
• W2045453312 cites W2065748621 @default.
• W2045453312 cites W2067157673 @default.
• W2045453312 cites W2068877344 @default.
• W2045453312 cites W2070916124 @default.
• W2045453312 cites W2072692689 @default.
• W2045453312 cites W2075088280 @default.
• W2045453312 cites W2076270223 @default.
• W2045453312 cites W2077226374 @default.
• W2045453312 cites W2078488797 @default.
• W2045453312 cites W2078686410 @default.
• W2045453312 cites W2080734156 @default.
• W2045453312 cites W2081529839 @default.
• W2045453312 cites W2083936576 @default.
• W2045453312 cites W2086555736 @default.
• W2045453312 cites W2087161612 @default.
• W2045453312 cites W2088196212 @default.
• W2045453312 cites W2088555681 @default.
• W2045453312 cites W2089562080 @default.
• W2045453312 cites W2092464307 @default.
• W2045453312 cites W2093944021 @default.
• W2045453312 cites W2094622999 @default.
• W2045453312 cites W2103420686 @default.
• W2045453312 cites W2143981217 @default.

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