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- W2045463968 abstract "The fluorescence excitation and sensitized phosphorescence excitation spectra of jet-cooled naphthalene clusters were measured. The intensity of the cluster bands in the sensitized phosphorescence excitation spectrum depends on both the cluster size and the excess vibrational energy. The intensity of the trimer is 1.3 times larger than that of the monomer in the 8̄10 region. However, the intensity of the tetramer is weaker than that of the monomer in the same excitation region. The trimer band intensity in the sensitized phosphorescence excitation spectrum decreases with an increase in the excitation energy compared with that in the fluorescence excitation spectrum. These results indicate that intersystem crossing of the clusters competes with faster relaxation at higher excitation energies. It is considered that the fast process is associated with the relaxation of the clusters to an excimer state. © 1997 Elsevier Science S.A." @default.
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- W2045463968 date "1997-06-01" @default.
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- W2045463968 title "Intersystem crossing in jet-cooled naphthalene clusters as studied by sensitized phosphorescence excitation spectroscopy" @default.
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- W2045463968 doi "https://doi.org/10.1016/s1010-6030(97)00045-2" @default.
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