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- W2045467241 abstract "Poly(pyridylureas) and poly(pyridylthioureas) were synthesized by reacting 2,6-diaminopyridine with phosgene and thiophosgene, respectively, using THF and pyridine as solvent. The synthesized polymers were characterized by IR-spectroscopy, elemental analysis, and X-ray photoelectron spectroscopy. Thermal stability of the polymers was determined by thermal degradation between 35°C and 700°C. The 50% weight loss of polypyridylureas was above 400°C while for the polypyridylthioureas it was above 450°C. Undoped poly(pyridylureas) and poly(pyridylthioureas) behave as semiconductors, σ = 10−9 (Ω cm)−1. After doping with I2 and SbF5, the electrical conductivity increases several orders of magnitude, σ = 10−7(Ω cm)−1. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007" @default.
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- W2045467241 date "2007-01-01" @default.
- W2045467241 modified "2023-10-01" @default.
- W2045467241 title "Synthesis and characterization of poly(pyridylurea) and poly(pyridylthiourea), potentially semiconducting polymers" @default.
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- W2045467241 doi "https://doi.org/10.1002/app.26209" @default.
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