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• W2045475863 abstract "Abstract 2,4-Dimethoxy- and 2,4-dibenzyloxy-5-lithiopyrimidines, obtained from the corresponding substituted 5-bromopyrimidines, react with trimethylsilyl chloride or trimethylstannyl chloride to give the appropriate 5-trimethylsilyl or 5-trimethylstannyl derivatives. The following compounds were synthesized by this reaction sequence: 2,4-dimethoxy-5-trimethylsilylpyrimidine (2), 2,4-dibenzyloxy-5-trimethylsilylpyrimidine (3), 2,4-dimethoxy-5-trimethylstannylpyrimidine (4), and 2,4-dibenzyloxy-5-trimethylstannylpyrimidine (5). Similarly, 6-chloro-2,4-dimethoxypyrimidine was converted into the 5-lithio derivative which subsequently gave 6-chloro-2,4-dimethoxy-5-trimethylsilylpyrimidine (6) and 6-chloro-2,4-dimethoxy-5-trimethylstannylpyrimidine (7). In a new modified synthesis of 5-trimethylsilyluracil (1), 2,4-dibenzyloxy-5-trimethylsilylpyrimidine (3) was smoothly converted into 1 by reaction with trimethylsilyl iodide." @default.
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• W2045475863 date "1988-03-01" @default.
• W2045475863 modified "2023-09-26" @default.
• W2045475863 title "Synthesis of silyl and stannyl pyrimidines" @default.
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• W2045475863 doi "https://doi.org/10.1016/0022-328x(88)80038-x" @default.
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