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- W2045485340 abstract "If color-centers diffuse into a NaCl-AgCl crystal, the Ag+ ions are reduced and precipitate as colloidal particles of metallic silver. Since this process seems to be quite analogous to the internal oxidation of binary metallic alloys, measurements were made to obtain the number and size of the silver particles vs. their distance from the surface of the crystal. The results were compared with the predictions of the theory of internal oxidation, and were found to confirm the analogy. Si des centres colorés diffusent dans un cristal NaCl-AgCl, les ions Ag+ sont réduits et précipités en particules colloïdales d'argent métallique. Comme ce processus paraît être tout à fait analogue à l'oxydation interne des alliages binaires métalliques, l'auteur a effectué des mesures du nombre et de la taille des particules d'argent en fonction de leur distance à la surface du cristal. Les résultats sont comparés aux valeurs prévues par la théorie de l'oxydation interne. L'analogie entre les deux processus est confirmée. Diffundieren Farbzentren in einen NaCl-AgCl-Kristall hinein, so werden die Ag+-Ionen reduziert und fallen als kolloidales metallisches Silber aus. Da dieser Fällungsvorgang dem der inneren Oxidation binärer metallischer Legierungen analog zu sein scheint, wurde die Zahl und Gröβe der Silberpartikel als Funktion ihres Abstandes von der Kristalloberfläche gemessen. Das Ergebnis wurde mit den Aussagen der Theorie der inneren Oxidation verglichen und die Analogie bestätigt." @default.
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- W2045485340 date "1971-07-01" @default.
- W2045485340 modified "2023-10-08" @default.
- W2045485340 title "The internal reduction of Ag+ centers in NaCl crystals" @default.
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- W2045485340 doi "https://doi.org/10.1016/0001-6160(71)90020-4" @default.
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