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- W2045486175 abstract "The cinnamyloxy and oxiranyl benzyl radicals were generated by photolysis of alkyl 4-nitrobenzenesulfenates. The yet unprecedented epoxide ring formation from a primary alkoxy radical was observed. Experimental evidence supports the fact that the mode of ring opening of the oxiranyl carbinyl radical system is thermodynamically driven. B3LYP/6-31G* calculations indicate that the closed form of the radical is ∼5 kcal/mol more stable than the open one." @default.
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- W2045486175 date "2000-04-12" @default.
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- W2045486175 title "Epoxide Formation by Ring Closure of the Cinnamyloxy Radical" @default.
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- W2045486175 doi "https://doi.org/10.1021/ol005749t" @default.
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