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- W2045496596 abstract "Abstract The deposition history, growth mechanism, structural, optical and surface morphological features of chemically deposited Hg x Pb 1 − x S (0 ⩽ x ⩽ 0.2) thin films prepared under optimized conditions are presented. Effect of growth parameter ( x ) on the film quality and properties has been studied. The resulting films appeared smooth, uniform and well adherent to the substrate and diffusely reflecting with color changing from grayish-brown to light-brown as x was varied from 0 to 0.2. The EDS analysis showed replacement of Pb 2+ atoms from PbS lattice by Hg 2+ atoms. The X-ray diffraction revealed crystalline nature with zinc blende type structure with predominant (2 0 0) orientation. Both interplanar distance and lattice parameter for (2 0 0) and (1 1 1) reflections increased with x in the alloyed range (0 ⩽ x ⩽ 0.035). SEM observations showed non-uniform distribution of well defined spherical grains; some of them diffused to form agglomeration/globule like structure. Analysis of the transmission spectra in the 500–3000 nm wavelength range showed 20–95% transmittance, absorption coefficient of the order of 10 4 –10 5 cm −1 and energy gap increased from 0.52 eV to 1.75 eV respectively for the change of x from 0 to 0.2." @default.
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- W2045496596 date "2014-06-01" @default.
- W2045496596 modified "2023-09-26" @default.
- W2045496596 title "Synthesis, structure and spectro-microscopic studies of polycrystalline HgxPb1−xS thin films grown by a chemical route" @default.
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- W2045496596 doi "https://doi.org/10.1016/j.jallcom.2014.01.006" @default.
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