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- W2045528021 abstract "Abstract Cyclosporin A ( 1 ) was O-alkylated selectively using phase transfer catalyzed reactions. With allyl chloride, metallyl chloride and propargyl bromide this lead to the ethers, 2 , 3 and 4 , respectively. With t-butyl bromoacetate the product was the ester 5 which was reduced to the alcohol 6 . With 2-(bromomethyl-propenoic acid methyl ester the ether 7 was obtained which was converted to 8 . The allylic ether alcohol 10 was prepared from 9 . This in turn was accessible from 1 and 1-chloro-2-chloromethyl-2-propene." @default.
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- W2045528021 date "1994-08-01" @default.
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- W2045528021 title "Preparation of functionalized ethers of cyclosporin A" @default.
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- W2045528021 doi "https://doi.org/10.1016/s0040-4039(00)78250-5" @default.
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