Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045542078> ?p ?o ?g. }
- W2045542078 endingPage "159" @default.
- W2045542078 startingPage "85" @default.
- W2045542078 abstract "A series of novel chloro-complexes of Mn2+, Co2+, Ni2+ and Fe3+ with 2,4,6-tris-(2-pyridyl)-1,3,5-triazine (L1) and thiourea (L2) with the formulae, [Mn(L1)Cl2(EtOH)]L2 (1), [Co(L1)Cl2(H2O)]L2.1/2H2O (2), [Ni(L1)Cl2(H2O)]L2.1/2H2O (3) and [Fe(L1)Cl3]L2 (4) were investigated utilizing convenient methods. Conversely, similar reaction resulted in complex with structure [Mn(L1)(OAc)(H2O)Cl]·H2O (5) in presence of sodium acetate. Pentagonal-bipyramidal geometry around Mn2+ ion is suggested. The solid state ESR spectra of Mn2+, Co2+ and Ni2+ complexes parameters show g|| > g┴ > 2.0023 indicating that the ground state is dx2-y2. Electronic spectra of two Mn2+ and the other complexes and the values of magnetic moments suggest octahedral geometry for complexes while pentagonal-pyramidal for [Mn(L1)Cl2(EtOH)]L2. Biological activity of complexes was tested versus alpathogenic bacteria (E. Coli, S. Aureus and C. Albicans). Further, the cytotoxic activity was screened for in vitro against (HeLa), (MCF-7), (HePG2) and (HeP-2). The role of ionic radii of the metal ion on the biological activity was investigated." @default.
- W2045542078 created "2016-06-24" @default.
- W2045542078 creator A5014912780 @default.
- W2045542078 creator A5032844848 @default.
- W2045542078 creator A5087799113 @default.
- W2045542078 date "1978-07-01" @default.
- W2045542078 modified "2023-09-23" @default.
- W2045542078 title "Actinide complexes with carboxylic acids" @default.
- W2045542078 cites W1493889572 @default.
- W2045542078 cites W1502878631 @default.
- W2045542078 cites W1543231308 @default.
- W2045542078 cites W1543599144 @default.
- W2045542078 cites W1596664407 @default.
- W2045542078 cites W164320924 @default.
- W2045542078 cites W1963909295 @default.
- W2045542078 cites W1964204826 @default.
- W2045542078 cites W1965455204 @default.
- W2045542078 cites W1965960708 @default.
- W2045542078 cites W1969317139 @default.
- W2045542078 cites W1970590011 @default.
- W2045542078 cites W1971337474 @default.
- W2045542078 cites W1971563724 @default.
- W2045542078 cites W1973837981 @default.
- W2045542078 cites W1973948137 @default.
- W2045542078 cites W1974945641 @default.
- W2045542078 cites W1976003581 @default.
- W2045542078 cites W1976533468 @default.
- W2045542078 cites W1976771250 @default.
- W2045542078 cites W1977622696 @default.
- W2045542078 cites W1977799334 @default.
- W2045542078 cites W1978382538 @default.
- W2045542078 cites W1980409173 @default.
- W2045542078 cites W1980773913 @default.
- W2045542078 cites W1981566437 @default.
- W2045542078 cites W1981688667 @default.
- W2045542078 cites W1982816386 @default.
- W2045542078 cites W1983897212 @default.
- W2045542078 cites W1984555581 @default.
- W2045542078 cites W1987083167 @default.
- W2045542078 cites W1988359341 @default.
- W2045542078 cites W1991100387 @default.
- W2045542078 cites W1991591239 @default.
- W2045542078 cites W1992812643 @default.
- W2045542078 cites W1993591592 @default.
- W2045542078 cites W1993914135 @default.
- W2045542078 cites W1994540134 @default.
- W2045542078 cites W1995006888 @default.
- W2045542078 cites W1998265917 @default.
- W2045542078 cites W199869374 @default.
- W2045542078 cites W1999157857 @default.
- W2045542078 cites W1999460017 @default.
- W2045542078 cites W2000096849 @default.
- W2045542078 cites W2001814184 @default.
- W2045542078 cites W2004301732 @default.
- W2045542078 cites W2005424045 @default.
- W2045542078 cites W2005603325 @default.
- W2045542078 cites W2005667433 @default.
- W2045542078 cites W2006342602 @default.
- W2045542078 cites W2007321257 @default.
- W2045542078 cites W2008733708 @default.
- W2045542078 cites W2008766951 @default.
- W2045542078 cites W2010909824 @default.
- W2045542078 cites W2010913165 @default.
- W2045542078 cites W2013528670 @default.
- W2045542078 cites W2013575777 @default.
- W2045542078 cites W2014162664 @default.
- W2045542078 cites W2014539894 @default.
- W2045542078 cites W2016210268 @default.
- W2045542078 cites W2016872338 @default.
- W2045542078 cites W2017239982 @default.
- W2045542078 cites W2018331591 @default.
- W2045542078 cites W2020993762 @default.
- W2045542078 cites W2021886893 @default.
- W2045542078 cites W2021896175 @default.
- W2045542078 cites W2022761105 @default.
- W2045542078 cites W2022929792 @default.
- W2045542078 cites W2024260496 @default.
- W2045542078 cites W2025320501 @default.
- W2045542078 cites W2027683384 @default.
- W2045542078 cites W2027957148 @default.
- W2045542078 cites W2029876982 @default.
- W2045542078 cites W2030330688 @default.
- W2045542078 cites W2031363716 @default.
- W2045542078 cites W2033552688 @default.
- W2045542078 cites W2033841555 @default.
- W2045542078 cites W2034708690 @default.
- W2045542078 cites W2034918235 @default.
- W2045542078 cites W2036409626 @default.
- W2045542078 cites W2037344395 @default.
- W2045542078 cites W2037509881 @default.
- W2045542078 cites W2037844214 @default.
- W2045542078 cites W2037905204 @default.
- W2045542078 cites W2039612534 @default.
- W2045542078 cites W2042701187 @default.
- W2045542078 cites W2042768574 @default.
- W2045542078 cites W2043614191 @default.
- W2045542078 cites W2045723346 @default.
- W2045542078 cites W2047429092 @default.