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- W2045552676 abstract "Some aspects of the low-temperature geochemistry of siderite are reviewed, especially the siderite—calcite solid solution. The understanding of this solid solution is limited by metastability, reaction kinetics and lack of experimental work. Also, loss of siderite by oxidation and acidification upon sampling and analysis limit the practical understanding of siderite behavior. Because of the lack of reliable direct evidence of siderite presence, results of the field study demonstrate the probable presence and mechanisms of formation of siderite through indirect aqueous-based methods: pH—pe diagram, saturation indices of minerals calculated through a speciation model, availability of reactants for precipitation reactions and stoichiometry of precipitation reactions. The mechanism of formation in the aquifer at the field site is the replacement of calcite, and both calcite and siderite occur at levels of less than 1 wt.%. Calculations show this minor amount of carbonate has a major effect on contaminant migration through pH neutralization. The replacement of calcite by siderite at the field site removes a substantial portion of the aquifer's neutralization capacity." @default.
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- W2045552676 date "1986-07-01" @default.
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- W2045552676 title "Trace amounts of siderite near a uranium-tailings impoundment, Elliot Lake, Ontario, Canada, and its implication in controlling contaminant migration in a sand aquifer" @default.
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- W2045552676 doi "https://doi.org/10.1016/0009-2541(86)90115-4" @default.
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