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- W2045559322 abstract "Light emission from the impact of Al+(1S,3P) ions on H2 molecules at 5.2 to 13.8 eVCM was spectrally analyzed. It was found to consist of two band systems. Of the known A 2Π–X 2Σ+ transition, numerous new bands were observed, allowing a first experimental determination of vibrational constants. In addition, a predicted B 2Σ+–X 2Σ+ system was observed for the first time. Relative emission cross sections for the two systems and for the 1S and 3P reactant species were measured. They parallel closely the trends in the isovalent system B++H2. One important difference is, however, the existence of a large (∼3.5 eV) activation barrier in the dominant Al++H2 reaction channel. This is explained in terms of adiabatic potential hypersurfaces." @default.
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- W2045559322 date "1986-07-01" @default.
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- W2045559322 title "Chemiluminescent reactions of second‐row atomic ions. I. Al<sup>+</sup>+H<sub>2</sub>→AlH<sup>+</sup>(<i>A</i> <sup>2</sup>Π, <i>B</i> <sup>2</sup>Σ<sup>+</sup>)+H" @default.
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- W2045559322 doi "https://doi.org/10.1063/1.451642" @default.
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