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- W2045563219 abstract "The shear strength of bonds between isotactic polypropylene and cellophane, formed under standard conditions, has beer studied as a function of cooling rates, following bond formation, and after ageing at temperatures up to 90°C. Rapid cooling produced cohesively failing bonds with shear strengths above 20 kg/em2. Weak, adhesively failing joints were produced under slow-cooling conditions. Strong bonds deteriorated when joints were aged at temperatures above 50°C, but further improvement in bond strength was observed upon ageing at lower temperatures. Experimental observations were consistent with the development of smectic structure in the polypropylene upon rapid cooling; a tendency for transcrystallization in slow-cooled joints was offset by the presence of weak boundary layers in the interface. Ageing produced further development of weak boundary layers and a transition from smectic to monoclinic crystallization in polypropylene. At higher ageing temperatures, the former effect seemed dominant; at lower temperatures, the structural change was assumed responsible for the observed improvement in bond strength." @default.
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- W2045563219 date "1977-07-01" @default.
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- W2045563219 title "Adhesion at polypropylene-cellophane interfaces" @default.
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- W2045563219 doi "https://doi.org/10.1002/pen.760170707" @default.
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