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- W2045563799 abstract "Phase transformations in vitreous and crystalline GeO2 (rutile) have been investigated up to ∼50 GPa and ∼1000°C by using a diamond anvil pressure cell coupled with a YAG laser heating system and in situ x-ray diffraction techniques. The results show that whereas the vitreous GeO2 transforms into a hexagonal phase at pressures ∼25 GPa, the crystalline GeO2 transforms into an orthorhombic phase at ∼28 GPa; the molar volume changes for the hexagonal and orthorhombic transformations are − 1.0% (at 25 GPa) and − 3.0% (at 28 GPa), respectively. When unloaded to 0.1 MPa, both the hexagonal and orthorhombic phases of GeO2 are retained, and the zero-pressure molar volume is 0.7% larger and 4.5% smaller than that of the rutile-structured GeO2, respectively. These results are in good agreement with previously published data." @default.
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- W2045563799 date "1983-08-01" @default.
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- W2045563799 title "High-pressure phase transformations in vitreous and crystalline GeO2 (rutile)" @default.
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- W2045563799 doi "https://doi.org/10.1016/0031-9201(83)90004-3" @default.
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