FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045572952> ?p ?o ?g. }

• W2045572952 endingPage "4806" @default.
• W2045572952 startingPage "4791" @default.
• W2045572952 abstract "The synthesis of a series of new ruthenium complexes based on the new PONOP ligands 1 and 10 ((C5H3N-1,3-(OPR2)2: 1, R = iPr; 10, R = tBu) is presented, including the stable trans-dihydride complexes (iPr-PONOP)Ru(H)2(PPh3) (4) and (tBu-PONOP)Ru(H)2(CO) (12) and the stable Ru(0) complexes (R-PONOP)Ru(CO)2 (6, R = iPr; 15, R = tBu). A surprisingly stable 16-electron Ru(0) complex (13) was formed by deprotonation of 12 with KOtBu. Complex 13 reacts with H2 to afford the cis-dihydride complex 12a, which isomerized to the trans-dihydride 12. Complex 13 reacted with CO to afford the saturated Ru(0) complex 15. Reaction of complex 12 with water led to hydrolysis of the phosphinite PONOP ligand and rearrangement to a dimeric product (14). Reaction of the trans-dihydride complex 4 with the electrophiles PhCOCl, MeI, and MeOTf led to abstraction of one of the hydride ligands, forming the monohydride complexes (iPr-PONOP)Ru(H)(PPh3)(X) (X = Cl (2), I (8a), OTf (8b)) together with benzaldehyde in the case of 2. Simi..." @default.
• W2045572952 created "2016-06-24" @default.
• W2045572952 creator A5000227894 @default.
• W2045572952 creator A5022394866 @default.
• W2045572952 creator A5049737397 @default.
• W2045572952 creator A5066809337 @default.
• W2045572952 creator A5081692819 @default.
• W2045572952 creator A5086773368 @default.
• W2045572952 date "2009-07-30" @default.
• W2045572952 modified "2023-10-16" @default.
• W2045572952 title "Formation of Stable <i>trans</i>-Dihydride Ruthenium(II) and 16-Electron Ruthenium(0) Complexes Based on Phosphinite PONOP Pincer Ligands. Reactivity toward Water and Electrophiles" @default.
• W2045572952 cites W1970765732 @default.
• W2045572952 cites W1973051984 @default.
• W2045572952 cites W1978183029 @default.
• W2045572952 cites W1981316027 @default.
• W2045572952 cites W1982768851 @default.
• W2045572952 cites W1983107490 @default.
• W2045572952 cites W1983644468 @default.
• W2045572952 cites W1984315233 @default.
• W2045572952 cites W1984974709 @default.
• W2045572952 cites W1985339238 @default.
• W2045572952 cites W1995399794 @default.
• W2045572952 cites W1996310246 @default.
• W2045572952 cites W2000737132 @default.
• W2045572952 cites W2003950386 @default.
• W2045572952 cites W2004390879 @default.
• W2045572952 cites W2005548967 @default.
• W2045572952 cites W2006016657 @default.
• W2045572952 cites W2006261739 @default.
• W2045572952 cites W2006412687 @default.
• W2045572952 cites W2009626516 @default.
• W2045572952 cites W2010799577 @default.
• W2045572952 cites W2010871030 @default.
• W2045572952 cites W2013160605 @default.
• W2045572952 cites W2013686648 @default.
• W2045572952 cites W2014315477 @default.
• W2045572952 cites W2019437299 @default.
• W2045572952 cites W2022431199 @default.
• W2045572952 cites W2023695570 @default.
• W2045572952 cites W2027301246 @default.
• W2045572952 cites W2027770184 @default.
• W2045572952 cites W2029102255 @default.
• W2045572952 cites W2030430586 @default.
• W2045572952 cites W2031352548 @default.
• W2045572952 cites W2032862281 @default.
• W2045572952 cites W2033383024 @default.
• W2045572952 cites W2038950330 @default.
• W2045572952 cites W2042263114 @default.
• W2045572952 cites W2043729794 @default.
• W2045572952 cites W2044627491 @default.
• W2045572952 cites W2050592102 @default.
• W2045572952 cites W2059557791 @default.
• W2045572952 cites W2062004872 @default.
• W2045572952 cites W2063208342 @default.
• W2045572952 cites W2063695452 @default.
• W2045572952 cites W2066945627 @default.
• W2045572952 cites W2067757437 @default.
• W2045572952 cites W2074051300 @default.
• W2045572952 cites W2076742047 @default.
• W2045572952 cites W2089906374 @default.
• W2045572952 cites W2091449628 @default.
• W2045572952 cites W2092949846 @default.
• W2045572952 cites W2093739290 @default.
• W2045572952 cites W2095022022 @default.
• W2045572952 cites W2103968992 @default.
• W2045572952 cites W2107400648 @default.
• W2045572952 cites W2115476655 @default.
• W2045572952 cites W2142981027 @default.
• W2045572952 cites W2315069987 @default.
• W2045572952 doi "https://doi.org/10.1021/om9004077" @default.
• W2045572952 hasPublicationYear "2009" @default.
• W2045572952 type Work @default.
• W2045572952 sameAs 2045572952 @default.
• W2045572952 citedByCount "81" @default.
• W2045572952 countsByYear W20455729522012 @default.
• W2045572952 countsByYear W20455729522013 @default.
• W2045572952 countsByYear W20455729522014 @default.
• W2045572952 countsByYear W20455729522015 @default.
• W2045572952 countsByYear W20455729522016 @default.
• W2045572952 countsByYear W20455729522017 @default.
• W2045572952 countsByYear W20455729522018 @default.
• W2045572952 countsByYear W20455729522019 @default.
• W2045572952 countsByYear W20455729522020 @default.
• W2045572952 countsByYear W20455729522021 @default.
• W2045572952 countsByYear W20455729522022 @default.
• W2045572952 countsByYear W20455729522023 @default.
• W2045572952 crossrefType "journal-article" @default.
• W2045572952 hasAuthorship W2045572952A5000227894 @default.
• W2045572952 hasAuthorship W2045572952A5022394866 @default.
• W2045572952 hasAuthorship W2045572952A5049737397 @default.
• W2045572952 hasAuthorship W2045572952A5066809337 @default.
• W2045572952 hasAuthorship W2045572952A5081692819 @default.
• W2045572952 hasAuthorship W2045572952A5086773368 @default.
• W2045572952 hasConcept C142724271 @default.
• W2045572952 hasConcept C155647269 @default.
• W2045572952 hasConcept C161790260 @default.
• W2045572952 hasConcept C178790620 @default.
• W2045572952 hasConcept C185592680 @default.

• next