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- W2045587321 abstract "The nmr 1H spectra of dichloromethane solutions of dimethylphenylphosphine containing TiCl4 at several ratios suggest the existence of fast equilibria involving the 2:1 and the 1:1 adducts. The existence of the latter compound was established by its isolations in an analytically pure state. 1:1 adducts of other tertiary phosphines are also reported. The temperature effect on the positions of the peaks observed at low phosphine: TiCl4 ratios is suggested to be due to be occurrence of an additional equilibrium involving a chlorine-bridged binuclear adduct." @default.
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- W2045587321 date "1969-01-01" @default.
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- W2045587321 title "Tertiary phosphines adducts of titanium tetrachloride" @default.
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- W2045587321 doi "https://doi.org/10.1016/s0020-1693(00)92505-2" @default.
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