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• W2045587582 endingPage "2290" @default.
• W2045587582 startingPage "2282" @default.
• W2045587582 abstract "Six complexes containing the 2,2′-biimidazole-like ligand and chloride, namely, trans-[Ni(H2biim)2(H2O)2]Cl2 (1), trans-[Co1.5(H2biim)3(H2O)3]Cl3 (2), [Zn(H2biim)2Cl]Cl (3), [Ni2(H2bbim)4(bbim)]Cl2 (4), [Co(H2bbim)3]Cl2·2H2O (5), and [Zn2(Hbbim)2(bbim)0.5Cl] (6) (where H2biim = 2,2′-biimidazole, H2bbim = 2,2′-bibenzimidazole) have been synthesized by the reactions of the H2biim or H2bbim ligand with the metal chloride salts. The structures of the complexes were determined by single-crystal X-ray diffraction analyses, and the results revealed that the distances of N···Cl varied from 3.10 to 3.29 Å and the angles of N−H···Cl varied from 148 to 169°, O···Cl varied from 3.09 to 3.16 Å, O−H···Cl varied from 151 to 178°, C···Cl varied from 3.49 to 3.69 Å, and C−H···Cl varied from 122 to 167°. The chloride may act as a multi hydrogen bonded acceptor varying from 3 to 6, resulting in an important collective contribution to cohesion. The data observed in this study seem to suggest that a variety of X−H···Cl (X = N, O, and C) synthons identified here play a crucial role in the formation and further stabilization of supramolecular architecture, for instance, to link the discrete (0D) or low-dimensional (1D) entities into high-dimensional frameworks. In particular, the coplanar [(H2O)2Cl2]2− guests are encapsulated in the cavities formed by four [Co(H2bbim)3]2+ cations and stabilized via accepting 6-fold hydrogen bonds from three H2bbim ligands in 5. The distance between the chloride anion and the imidazolyl ring (Cl···centroid, 3.30 Å and 80°) demonstrates the possible existence of Cl···π (imidazolyl) charge-assisted interactions because the coordination of a positively charged Co(II) ion greatly enhances the electron-deficient character of the imidazolyl ring and provides sufficient polarization to produce an anion−π charge-assisted interaction." @default.
• W2045587582 created "2016-06-24" @default.
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• W2045587582 creator A5088008447 @default.
• W2045587582 date "2008-05-28" @default.
• W2045587582 modified "2023-09-25" @default.
• W2045587582 title "Syntheses and Crystal Structures of Metal Complexes with 2,2′-Biimidazole-like Ligand and Chloride: Investigation of X−H···Cl (X = N, O, and C) Hydrogen Bonding and Cl−π (imidazolyl) Interactions" @default.
• W2045587582 cites W1608721379 @default.
• W2045587582 cites W1908930975 @default.
• W2045587582 cites W1964004579 @default.
• W2045587582 cites W1971360653 @default.
• W2045587582 cites W1972646318 @default.
• W2045587582 cites W1977745573 @default.
• W2045587582 cites W1981463752 @default.
• W2045587582 cites W1984445583 @default.
• W2045587582 cites W1988752229 @default.
• W2045587582 cites W1991749592 @default.
• W2045587582 cites W1995704270 @default.
• W2045587582 cites W1998921607 @default.
• W2045587582 cites W2000957081 @default.
• W2045587582 cites W2006668355 @default.
• W2045587582 cites W2012567403 @default.
• W2045587582 cites W2013564410 @default.
• W2045587582 cites W2014901786 @default.
• W2045587582 cites W2016185972 @default.
• W2045587582 cites W2022407184 @default.
• W2045587582 cites W2023556042 @default.
• W2045587582 cites W2024314990 @default.
• W2045587582 cites W2031868598 @default.
• W2045587582 cites W2037155785 @default.
• W2045587582 cites W2040564787 @default.
• W2045587582 cites W2044422763 @default.
• W2045587582 cites W2045769467 @default.
• W2045587582 cites W2048213864 @default.
• W2045587582 cites W2051073838 @default.
• W2045587582 cites W2053405510 @default.
• W2045587582 cites W2059212878 @default.
• W2045587582 cites W2060226568 @default.
• W2045587582 cites W2060494336 @default.
• W2045587582 cites W2065357765 @default.
• W2045587582 cites W2075044440 @default.
• W2045587582 cites W2078455756 @default.
• W2045587582 cites W2080196027 @default.
• W2045587582 cites W2082269735 @default.
• W2045587582 cites W2084310019 @default.
• W2045587582 cites W2084669405 @default.
• W2045587582 cites W2084844103 @default.
• W2045587582 cites W2086712461 @default.
• W2045587582 cites W2090705431 @default.
• W2045587582 cites W2092282301 @default.
• W2045587582 cites W2095143383 @default.
• W2045587582 cites W2101522374 @default.
• W2045587582 cites W2105249240 @default.
• W2045587582 cites W2110574274 @default.
• W2045587582 cites W2127452039 @default.
• W2045587582 cites W2131214655 @default.
• W2045587582 cites W2135183779 @default.
• W2045587582 cites W2136585666 @default.
• W2045587582 cites W2137207432 @default.
• W2045587582 cites W2142594455 @default.
• W2045587582 cites W2142597358 @default.
• W2045587582 cites W2147304506 @default.
• W2045587582 cites W2147709549 @default.
• W2045587582 cites W2148624934 @default.
• W2045587582 cites W2157585198 @default.
• W2045587582 cites W2163534608 @default.
• W2045587582 cites W2168006877 @default.
• W2045587582 cites W2951382260 @default.
• W2045587582 doi "https://doi.org/10.1021/cg700980v" @default.
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