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- W2045587687 abstract "A series of manganese(III) complexes of aryl substituted N2O2 donor set Schiff base ligands has been prepared by the aerial oxidation of manganese(II) precursors. The resultants complexes of stoichiometry [MnL]C1O4·nH2O (where n = 1–3) have been thoroughly characterised by elemental analyses, infrared spectroscopy, fast atom bombardment (FAB) mass spectrometry, magnetic susceptibility measurements and paramagnetic 1H NMR. The crystal structure of [MnL7(H2O)2]ClO4·H4O, 1, shows it to consist of a polymeric array of roughly octahedtal [MnL7(H2O)2]+ cations linked via an intricate network of hydrogen bonds between the perchlorate counterion and the lattice water molecule. This hydrogen bonding is further enhanced by π-π stabilisation between the aryl rings of the Schiff base ligands. An attempt is made to rationalise the structural chemistry observed by us for complexes of this type." @default.
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- W2045587687 date "1996-09-01" @default.
- W2045587687 modified "2023-10-18" @default.
- W2045587687 title "The diversity observed in manganese(III) complexes of tetradentate Schiff base ligands: An assessment of structural trends" @default.
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- W2045587687 doi "https://doi.org/10.1016/0277-5387(96)00161-1" @default.
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