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• W2045596332 abstract "The asymmetric gold(I)-catalyzed ring expansion of 1-allenylcyclopropanols is described. The method provides synthetically valuable cyclobutanones with a vinyl-substituted quaternary stereogenic center in high enantioselectivities and yields. The method shows a broad substrate scope, tolerating protected alcohols and amines, alkenes, unsaturated esters, and acetals. The reaction is easily adjustable to large-scale synthesis, leading to product formation without significant loss of selectivity or yield with only 0.5 mol% catalyst loading." @default.
• W2045596332 created "2016-06-24" @default.
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• W2045596332 date "2009-06-16" @default.
• W2045596332 modified "2023-10-07" @default.
• W2045596332 title "Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols" @default.
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• W2045596332 doi "https://doi.org/10.1021/ja904055z" @default.
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