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- W2045597952 abstract "Pair interaction parameters like the second virial coefficient A2 or the Flory-Huggins parameter χ are influenced by inter- and intramolecular contacts. The paper discusses a model in which A2 linearly depends on M−(a−0.5), where a is the exponent in the Mark-Houwink relation. From this dependence, the two components of χ, namely χinter and χintra, were evaluated and their values, their interdependence and their variation with the thermodynamic quality of the solvent were determined. The evaluation of numerous literature data confirms the model." @default.
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- W2045597952 date "1994-09-01" @default.
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- W2045597952 title "Influence of inter- and intramolecular contacts on the second virial coefficient" @default.
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- W2045597952 doi "https://doi.org/10.1016/0014-3057(94)90202-x" @default.
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