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- W2045603980 endingPage "10239" @default.
- W2045603980 startingPage "10226" @default.
- W2045603980 abstract "The discovery of new methods for the synthesis of classes of potentially bioactive molecules remains an important goal for synthetic chemists. Vinylsulfonium salts have been used for the synthesis of a wide variety of small heterocyclic motifs; however, further developments to this important class of reagents has been focused on reaction with new substrates rather than development of new vinylsulfonium salts. We herein report the synthesis of a range of α-substituted vinylsulfonium tetraphenylborates (10 examples) in a 3 step procedure from commercially available styrenes. The important role of the tetraphenylborate counterion on the stability and accessibility of the vinylsulfonium salts is also detailed. The α-substituted vinylsulfonium tetraphenylborates gave good to excellent yields in the epoxyannulation of β-amino ketones (15 examples) and the cyclopropanation of allylic amines (4 examples). Hydrogenation of an epoxyannulation product proceeded with good diastereoselectivity." @default.
- W2045603980 created "2016-06-24" @default.
- W2045603980 creator A5003629087 @default.
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- W2045603980 creator A5071108241 @default.
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- W2045603980 date "2014-10-13" @default.
- W2045603980 modified "2023-10-07" @default.
- W2045603980 title "Synthesis of α-Substituted Vinylsulfonium Salts and Their Application as Annulation Reagents in the Formation of Epoxide- and Cyclopropane-Fused Heterocycles" @default.
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- W2045603980 cites W1969487950 @default.
- W2045603980 cites W1969718983 @default.
- W2045603980 cites W1974683038 @default.
- W2045603980 cites W1983028289 @default.
- W2045603980 cites W1993276724 @default.
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- W2045603980 cites W2017072339 @default.
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- W2045603980 cites W2033522651 @default.
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- W2045603980 cites W2332742076 @default.
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- W2045603980 cites W2949726425 @default.
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- W2045603980 doi "https://doi.org/10.1021/jo501885z" @default.
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- W2045603980 hasPublicationYear "2014" @default.
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