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• W2045609560 abstract "Controlled anionic ring-opening polymerization of ϵ-caprolactone (ϵ-CL) in toluene using self-complementary quadruple hydrogen bonding array 2-ureido-4[1H]-pyrimidinone (UPy)-functionalized initiators with stannous(II) octanoate has been achieved to yield UPy−poly(ϵ-caprolactone) chains capable of undergoing supramolecular self-assembly. Molecular weights of these polymers varied from 2000 to 20 000 g/mol and were determined using 1H NMR end-group analysis as well as gel permeation chromatography. Furthermore, using Ubbelohde solution viscometry, samples demonstrated a marked increase in viscosity-average molecular weight when measured in chloroform, indicating that the UPy chain ends are in a dimerized form when compared to polymer solutions in dimethylformamide (DMF)." @default.
• W2045609560 created "2016-06-24" @default.
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• W2045609560 date "2008-05-20" @default.
• W2045609560 modified "2023-10-07" @default.
• W2045609560 title "Controlled Ring-Opening Polymerization Initiated via Self-Complementary Hydrogen-Bonding Units" @default.
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• W2045609560 doi "https://doi.org/10.1021/ma702699t" @default.
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