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- W2045615484 abstract "The formation of germanate phases with the mullite structure [Ga6Ge2O13, Al6Ge2O13 and (Ga,Al)6Ge2O13] from oxide mixtures and hybrid sol–gel precursors was studied by thermal analysis, XRD, IR spectroscopy and multinuclear MAS NMR. The course of the thermal reactions in all the Ga-containing oxide mixtures, irrespective of the starting composition, is dominated by the intermediate formation below 1150 °C of α- and β-Ga4GeO8 and by the volatilization of GeO2 at higher temperatures. In oxide mixtures containing alumina, Ga incorporation in the mullite-type phase occurs only above 1150 °C. IR spectroscopy confirms the incorporation of both Al and Ga into the mullite-type structure at higher temperature. No reaction with Ga2O3 occurred where the GeO2 was replaced by SiO2." @default.
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- W2045615484 date "2000-01-01" @default.
- W2045615484 modified "2023-09-27" @default.
- W2045615484 title "The system Ga2O3(Al2O3)–GeO2(SiO2) studied by NMR, XRD, IR and DTA" @default.
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- W2045615484 doi "https://doi.org/10.1039/a907541k" @default.
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