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• W2045622099 abstract "Reported here is a rare example of enantioselective processes between organic racemic ligands (dl-camphorates) with in situ formed chiral metal complexes. Such enantioselectivity leads to a double spontaneous resolution of two pairs of distinctly different racemates [the ΛΔ-Zn(Htea) units and the dl-camphorate ligands] into two chiral three-dimensional frameworks containing only one enantiommeric form from each racemate. This work demonstrates unique enantioselectivity in the self-assembly of metal−organic frameworks containing multiple chiral features, which points to a new avenue for the preparation of chiral framework materials and for the resolution of racemates." @default.
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• W2045622099 date "2009-06-19" @default.
• W2045622099 modified "2023-09-25" @default.
• W2045622099 title "Spontaneous Resolution of Racemic Camphorates in the Formation of Three-Dimensional Metal−Organic Frameworks" @default.
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• W2045622099 doi "https://doi.org/10.1021/ic900918z" @default.
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