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- W2045627587 abstract "When a solution of natural rubber hydrocarbon is cold vulcanized with sulfur monochloride, a gel is formed. The rate of gel formation is used to characterize the rate of reaction between rubber and sulfur monochloride and a preliminary kinetic investigation is described. It is shown that the reaction is accelerated by compounds normally used for speeding up sulfur (hot) vulcanization, and it is suggested that these function by virtue of their possessing an active hydrogen atom. Several series of simple compounds, containing the groups SH, OH, and NH2, are shown to function as effective accelerators and their activity is attributed to the presence of a labile hydrogen atom in the molecule RXH, where R = organic radical and X = S, O, or N. The absence of a direct relationship between accelerating power and basic or acidic strength suggests a free radical mechanism of accelerator action, based upon the process ${rm R} - {rm X} - {rm H } to {rm R} - mathop {{rm X }}limits^ * {rm + }mathop {{rm H }}limits^ * $." @default.
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- W2045627587 date "1954-08-01" @default.
- W2045627587 modified "2023-10-12" @default.
- W2045627587 title "Vulcanization of crepe rubber by sulfur monochloride. Part I. The gelation method" @default.
- W2045627587 doi "https://doi.org/10.1002/pol.1954.120147404" @default.
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