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• W2045630815 abstract "An electronic transition of iron in magnesiowustite has been studied with synchrotron Mossbauer and x-ray emission spectroscopies under high pressures. Synchrotron Mossbauer studies show that the quadrupole splitting disappears and the isomer shift drops significantly across the spin-paring transition of iron in $({mathrm{Mg}}_{0.75},{mathrm{Fe}}_{0.25})mathrm{O}$ between 52 and $70phantom{rule{0.3em}{0ex}}mathrm{GPa}$. Based upon current results and percolation theory, we reexamine the high-pressure phase diagram of $(mathrm{Mg},mathrm{Fe})mathrm{O}$ and find that iron-iron exchange interaction plays an important role in stabilizing the high-spin state of iron in $mathrm{FeO}$-rich $(mathrm{Mg},mathrm{Fe})mathrm{O}$." @default.
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• W2045630815 date "2006-03-15" @default.
• W2045630815 modified "2023-10-03" @default.
• W2045630815 title "Pressure-induced electronic spin transition of iron in magnesiowustite-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mo>(</mml:mo><mml:mi>Mg</mml:mi><mml:mo>,</mml:mo><mml:mi>Fe</mml:mi><mml:mo>)</mml:mo><mml:mi mathvariant=normal>O</mml:mi></mml:mrow></mml:math>" @default.
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• W2045630815 doi "https://doi.org/10.1103/physrevb.73.113107" @default.
• W2045630815 hasPublicationYear "2006" @default.
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