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- W2045643172 abstract "Four new polymeric supports with 3- and 6-carbon atom spacers and triazene linkers derived from meta- and para-aminophenol were synthesized from commercial Merrifield polymer. The supports could be used for immobilization of secondary amines in SPOS. A new strategy based on the use of diethylamine triazenes as masked precursors for the generation of polymer-supported diazonium ions was used. The performance of the new linkers was tested on Grignard and aldol reactions of solid-phase immobilized nortropinone. The new supports with C3-T2 linkers gave products with better yields and purities than the classical T2 supports or the supports with the C6-T2 linkers." @default.
- W2045643172 created "2016-06-24" @default.
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- W2045643172 date "2003-03-01" @default.
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- W2045643172 title "Synthesis of polymeric supports with spacer-modified triazene linkers: aldol and Grignard reactions of immobilized nortropinone" @default.
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- W2045643172 doi "https://doi.org/10.1016/s0040-4039(03)00345-9" @default.
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