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- W2045643572 abstract "The p-toluenesulfonate of 7,8-dihydro-5(6H)quinoloneoxime(3) was subjected of a Beckmann rearràngement. The resulting 2,3,4,5-tetrahydro-1H-pyrido[3,2-b]azepin-2-one (4) was reduced with lithium aluminum hydride affording 2,3,4,5-tetrahydro-1H-pyrido[3,2-b] azepine (5). 5,6-l)ihydro-8(7H)quinolone (7), obtained by oxidation of 5,6,7,8-tetrahydro-8-quinolinol (6), was converted into the p-toluenesulfonate of 5,6-dihydro-8(7H)quinolone oxitne (9). Similarly the latter compound could be rearranged into 2,3,4,5-letrahydro-1H-pyrido [2,3-b] azepin-2-one (10) which on reduction produced 2,3,4,5-tetrahydro-1H-pyrido [2,3-b] azepine (11)." @default.
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- W2045643572 date "1978-03-01" @default.
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- W2045643572 title "Tetrahydropyridoazepines and tetrahydropyridoazepinones from the corresponding dihydroquinolones" @default.
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- W2045643572 doi "https://doi.org/10.1002/jhet.5570150213" @default.
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