FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045643669> ?p ?o ?g. }

• W2045643669 endingPage "80" @default.
• W2045643669 startingPage "74" @default.
• W2045643669 abstract "A permanent polycation, polydiallyldimethylammonium (PDADMA), is applied as a linear, polymeric, replaceable, and nonmicellar pseudostationary phase for the separation of neutral analytes by capillary electrokinetic chromatography. It is shown that this polymer used in the background electrolyte is able to separate the analytes even if it does not form micelles under the given conditions. The most favorable aspect for practical use lays in the simple replacement of the separation media after each run, thus generating highly reproducible conditions. To determine the capacity factors of the analytes, a new method, based on an isotachophoretic regime, has been introduced for the measurement of the electrophoretic mobility of the polymeric pseudo-stationary phase. The capacity factors in the separation system, derived from the mobilities of the polymer, the electroosmotic flow, and the mobilities of 15 individual aromatic analytes, range between 0.3 and 1.2 for the given separation media (aqueous solution of acetate buffer, pH 5.2, with 4% w/w PDADMA). The type of interaction in the pseudochromatographic system was clarified from solvation parameters based on the linear free energy relationship model. It was found that π and n electron interactions and hydrogen-bond basicity of the polymer, as compared with the aqueous bulk phase, are the main cause of retention of the analytes." @default.
• W2045643669 created "2016-06-24" @default.
• W2045643669 creator A5002011879 @default.
• W2045643669 creator A5024509634 @default.
• W2045643669 creator A5049292375 @default.
• W2045643669 creator A5053201463 @default.
• W2045643669 creator A5056898153 @default.
• W2045643669 creator A5079792238 @default.
• W2045643669 date "1999-11-19" @default.
• W2045643669 modified "2023-10-13" @default.
• W2045643669 title "Capillary Electrokinetic Chromatography with Charged Linear Polymers as a Nonmicellar PseudoStationary Phase: Determination of Capacity Factors and Characterization by Solvation Parameters" @default.
• W2045643669 cites W135885309 @default.
• W2045643669 cites W1966838267 @default.
• W2045643669 cites W1967441316 @default.
• W2045643669 cites W1970852990 @default.
• W2045643669 cites W1973036269 @default.
• W2045643669 cites W1975605911 @default.
• W2045643669 cites W1980533594 @default.
• W2045643669 cites W1982688043 @default.
• W2045643669 cites W1987929839 @default.
• W2045643669 cites W1988295585 @default.
• W2045643669 cites W1988848749 @default.
• W2045643669 cites W1996776722 @default.
• W2045643669 cites W1999000343 @default.
• W2045643669 cites W1999082318 @default.
• W2045643669 cites W2004385082 @default.
• W2045643669 cites W2008912862 @default.
• W2045643669 cites W2009374012 @default.
• W2045643669 cites W2013068831 @default.
• W2045643669 cites W2018612325 @default.
• W2045643669 cites W2033037654 @default.
• W2045643669 cites W2051925947 @default.
• W2045643669 cites W2053680865 @default.
• W2045643669 cites W2056268496 @default.
• W2045643669 cites W2056559487 @default.
• W2045643669 cites W2059405014 @default.
• W2045643669 cites W2064267477 @default.
• W2045643669 cites W2163763334 @default.
• W2045643669 doi "https://doi.org/10.1021/ac990979a" @default.
• W2045643669 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10655637" @default.
• W2045643669 hasPublicationYear "1999" @default.
• W2045643669 type Work @default.
• W2045643669 sameAs 2045643669 @default.
• W2045643669 citedByCount "29" @default.
• W2045643669 countsByYear W20456436692014 @default.
• W2045643669 countsByYear W20456436692016 @default.
• W2045643669 crossrefType "journal-article" @default.
• W2045643669 hasAuthorship W2045643669A5002011879 @default.
• W2045643669 hasAuthorship W2045643669A5024509634 @default.
• W2045643669 hasAuthorship W2045643669A5049292375 @default.
• W2045643669 hasAuthorship W2045643669A5053201463 @default.
• W2045643669 hasAuthorship W2045643669A5056898153 @default.
• W2045643669 hasAuthorship W2045643669A5079792238 @default.
• W2045643669 hasConcept C10390740 @default.
• W2045643669 hasConcept C113196181 @default.
• W2045643669 hasConcept C121332964 @default.
• W2045643669 hasConcept C145148216 @default.
• W2045643669 hasConcept C147789679 @default.
• W2045643669 hasConcept C148093993 @default.
• W2045643669 hasConcept C17525397 @default.
• W2045643669 hasConcept C178790620 @default.
• W2045643669 hasConcept C184651966 @default.
• W2045643669 hasConcept C185592680 @default.
• W2045643669 hasConcept C186293402 @default.
• W2045643669 hasConcept C196806460 @default.
• W2045643669 hasConcept C27703432 @default.
• W2045643669 hasConcept C2900643 @default.
• W2045643669 hasConcept C40250595 @default.
• W2045643669 hasConcept C43617362 @default.
• W2045643669 hasConcept C44280652 @default.
• W2045643669 hasConcept C49511088 @default.
• W2045643669 hasConcept C521977710 @default.
• W2045643669 hasConcept C68801617 @default.
• W2045643669 hasConcept C97355855 @default.
• W2045643669 hasConceptScore W2045643669C10390740 @default.
• W2045643669 hasConceptScore W2045643669C113196181 @default.
• W2045643669 hasConceptScore W2045643669C121332964 @default.
• W2045643669 hasConceptScore W2045643669C145148216 @default.
• W2045643669 hasConceptScore W2045643669C147789679 @default.
• W2045643669 hasConceptScore W2045643669C148093993 @default.
• W2045643669 hasConceptScore W2045643669C17525397 @default.
• W2045643669 hasConceptScore W2045643669C178790620 @default.
• W2045643669 hasConceptScore W2045643669C184651966 @default.
• W2045643669 hasConceptScore W2045643669C185592680 @default.
• W2045643669 hasConceptScore W2045643669C186293402 @default.
• W2045643669 hasConceptScore W2045643669C196806460 @default.
• W2045643669 hasConceptScore W2045643669C27703432 @default.
• W2045643669 hasConceptScore W2045643669C2900643 @default.
• W2045643669 hasConceptScore W2045643669C40250595 @default.
• W2045643669 hasConceptScore W2045643669C43617362 @default.
• W2045643669 hasConceptScore W2045643669C44280652 @default.
• W2045643669 hasConceptScore W2045643669C49511088 @default.
• W2045643669 hasConceptScore W2045643669C521977710 @default.
• W2045643669 hasConceptScore W2045643669C68801617 @default.
• W2045643669 hasConceptScore W2045643669C97355855 @default.
• W2045643669 hasIssue "1" @default.
• W2045643669 hasLocation W20456436691 @default.
• W2045643669 hasLocation W20456436692 @default.

• next