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- W2045651192 abstract "The nonstoichiometric perovskite Sr2LaFe3O8+y (0 < y < 0.6) has been studied by Mossbauer spectroscopy, X-ray powder diffraction, and magnetic susceptibility techniques. Evidence was found for two new ordered vacancy phases. Orthorhombic Sr2LaFe3O8 is an antiferromagnet (TN = 715 ± 5 K), and is believed to contain layers of iron cations in tetrahedral coordination, each separated by two layers in octahedral coordination to oxygen. Mossbauer data gave clear indications of a second phase which was less well defined, but appears to have a range of stoichiometry below the ideal composition of Sr2LaFe3O8.5 and orders antiferromagnetically at about 500 K. This “tetragonal” phase shows considerable similarity to the previously reported SrFeO2.75, and the possibility of a structural relationship is discussed." @default.
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- W2045651192 date "1989-03-01" @default.
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- W2045651192 title "A study of the ordering of oxygen vacancies in the nonstoichiometric perovskite Sr2LaFe3O8+y by Mössbauer spectroscopy and a comparison with SrFeO3−y" @default.
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- W2045651192 doi "https://doi.org/10.1016/0022-4596(89)90252-1" @default.
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