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- W2045673525 abstract "The iminium salt [Me2NCMe2][BF4] (4BF4) adds to the reductively activated η4-benzene ligand in [Cr(η4-C6H6)(CO)3]2- (22-) to give the aminoalkyl-substituted η5-cyclohexadienide Cr(0) complex [Cr(η5-C6H6)(CMe2NMe2)(CO)3]- (5-). The unusual upfield chemical shift in NMR spectra of the methyl protons and carbons, which are positioned right above the cyclohexadienide ligand by an exo-addition, suggests a magnetic shielding effect indicative of a modest ring current despite the open conjugation of the cyclohexadienyl ligand. The analogous Mn(1) complex [Mn(η5-C6H6)(CMe2NMe2)(CO)3] (6) has been crystallographically characterized." @default.
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- W2045673525 date "2003-06-28" @default.
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- W2045673525 title "Addition of the Iminium Salt [Me<sub>2</sub>NCMe<sub>2</sub>][BF<sub>4</sub>] to the Reductively Activated Benzene in [Cr(η<sup>4</sup>-C<sub>6</sub>H<sub>6</sub>)(CO)<sub>3</sub>]<sup>2</sup><sup>-</sup>" @default.
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- W2045673525 doi "https://doi.org/10.1021/om010302p" @default.
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