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- W2045677916 abstract "Copper(II) azido complex [CuL(μ-1,3-N3)]n (1) of a NNO donor tridentate Schiff base (HL = 2-[1-(methylamino-ethylimino)-methyl]-phenol containing single end-to-end μ-1,3-azido bridged 1D infinite chain has been synthesized and characterized by elemental analysis, FT-IR spectroscopy. X-ray single crystal structure analysis reveals that in 1, the central copper(II) ion displays a distorted square pyramidal coordination geometry and are linked by single EE azide bridges forming chains running parallel to the crystallographic b axis. The magnetic interaction revealed that 1 is antiferromagnetic in nature (J = −19.5 (±0.2) cm−1). The catalytic activity of the complex is investigated in a series of solvents for the oxidation of olefins using tert-butyl-hydroperoxide as oxidant. The results showed highest selectivity for 1 in acetonitrile medium." @default.
- W2045677916 created "2016-06-24" @default.
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- W2045677916 date "2014-01-01" @default.
- W2045677916 modified "2023-10-12" @default.
- W2045677916 title "Single end to end azido bridged adduct of a tridentate schiff base copper(II) complex: Synthesis, structure, magnetism and catalytic studies" @default.
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- W2045677916 doi "https://doi.org/10.1016/j.ica.2013.09.032" @default.
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