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• W2045687636 abstract "Abstract Host effect on the intercalation of iron chloride(III) in its nitoromethane (NM) solution was investigated by using host carbons heat-treated at different temperatures, cokes with random orientation and pyrolytic carbons with planar one. Cokes heat-treated below 1900°C were not intercalated even in high concentration solution of FeCl3 (4.8 M). The reactivity of cokes heat-treated above 2100°C was found to be strongly dependent on the concentration of FeCl3 in the solution; the less crystallized coke needed the higher concentration of FeCl3 to be intercalated, and the smaller stage number of resultant intercalation compound from the coke heat-treated at a temperature was obtained in the higher concentration of solution. On the other hand, pyrolytic carbons behaved quite differently; all of them could react even in the 0.6 M solution of FeCl3, where any cokes did not react, to give the same stage-3 structure independent on the crystallinity. These different reactivities of hosts for the intercalation of FeCl3 in NM were discussed by comparing with those for other intercalations as reported previously." @default.
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• W2045687636 date "1999-02-01" @default.
• W2045687636 modified "2023-10-15" @default.
• W2045687636 title "Different reactivity of carbon materials for intercalation of iron chloride in its nitromethane solution" @default.
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• W2045687636 doi "https://doi.org/10.1016/s0379-6779(98)01480-5" @default.
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