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• W2045689916 abstract "Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = −CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki–Miyaura coupling between aryl bromides and phenyl boronic acid." @default.
• W2045689916 created "2016-06-24" @default.
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• W2045689916 creator A5038507186 @default.
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• W2045689916 date "2008-04-01" @default.
• W2045689916 modified "2023-10-14" @default.
• W2045689916 title "Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)" @default.
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• W2045689916 doi "https://doi.org/10.1016/j.jorganchem.2007.11.031" @default.
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