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- W2045704535 startingPage "4449" @default.
- W2045704535 abstract "The c-axis compressibility of the stage-1 alkaline-earth-metal intercalation compound ${mathrm{BaC}}_{6}$, determined from pressure-dependent (00L) neutron diffraction, is 0.77ifmmodetimeselsetexttimesfi{}${10}^{mathrm{ensuremath{-}}12}$ ${mathrm{cm}}^{2}$/dyn, the lowest of any graphite intercalation compound. In-plane diffraction at 1 bar shows that the in-plane C---C bond length is expanded 1.3% relative to graphite. Both results are consistent with valence and core-level x-ray photoemission experiments and band-structure theory; approximately one of the two Ba(6s) electrons is transferred to a graphitic ${ensuremath{pi}}^{mathrm{*}}$ conduction band, while s-d hybridization internal to the Ba site takes up the rest. The localized s-d charge accounts in part for the low compressibility." @default.
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- W2045704535 date "1987-09-15" @default.
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- W2045704535 title "Neutron-diffraction studies of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>BaC</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>:<i>c</i>-axis compressibility, carbon<i>–</i>carbon bond length, and charge transfer" @default.
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- W2045704535 doi "https://doi.org/10.1103/physrevb.36.4449" @default.
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