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• W2045706543 startingPage "7185" @default.
• W2045706543 abstract "We present results of a high-pressure photoluminescence study of Mn- and Ca-doped gadolinium gallium garnet (GGG) crystals. Since the Mn4+ ion has the same electronic structure of the open 3d3 shell as Cr3+, its spectroscopic properties are expected to be similar to those of the Cr-doped GGG. We observed the luminescence R-lines of various Mn4+ centres in GGG. In the 0–118 kbar pressure range those R-lines shift linearly to lower energies. The pressure coefficients are of the order of 2 cm−1 kbar−1, about three times larger than that for Cr3+ ions. This fact can be explained by different strength of coupling of isoelectronic Cr3+ and Mn4+ ions with GGG host. The changes of the radiative decay times of the Mn4+ centres as a function of pressure are fitted with a theoretical model." @default.
• W2045706543 created "2016-06-24" @default.
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• W2045706543 date "2005-11-01" @default.
• W2045706543 modified "2023-10-13" @default.
• W2045706543 title "Influence of high pressure on the luminescence transitions of Mn⁴⁺-doped gadolinium gallium garnet" @default.
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• W2045706543 doi "https://doi.org/10.1088/0953-8984/17/46/003" @default.
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