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- W2045708246 abstract "Abstract Aldehydes undergo smooth coupling with ethyl diazoacetate in the presence of 5 mol% silver substituted tungstophosphoric acid (AgTPA) under mild conditions to furnish β-ketoesters in high yields and with high selectivity via C–H insertion. This method is very useful for the preparation of β-ketoesters from both electron-rich as well as electron-deficient aromatic aldehydes. The catalyst can be recycled and reused for three to five subsequent runs with a gradual decrease of activity." @default.
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- W2045708246 date "2008-08-01" @default.
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- W2045708246 title "The silver salt of 12-tungstophosphoric acid: A mild and selective catalyst for the synthesis of β-ketoesters via C–H insertion" @default.
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- W2045708246 doi "https://doi.org/10.1016/j.catcom.2008.05.032" @default.
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