Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045708534> ?p ?o ?g. }
- W2045708534 endingPage "3124" @default.
- W2045708534 startingPage "3119" @default.
- W2045708534 abstract "Chemical ionization (CI) using the [ClMn(H2O)]+ reagent ion combined with collision-activated dissociation is demonstrated to allow the differentiation of isomeric alkanes (C8H18 and C9H20) and alkenes (C8H16) in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The [ClMn(H2O)]+ ion reacts with each isomeric hydrocarbon molecule to produce a water replacement product [hence providing molecular weight (MW) information], with no accompanying fragmentation. Differentiation of the isomers is achieved on the basis of the different fragmentation patterns observed upon sustained off-resonance irradiation collision-activated dissociation (SORI−CAD) of the isolated water replacement products. Upon activation, the weak bond of the hydrocarbon to ClMn+ is broken. ClMn+ is the major fragment ion for linear alkanes. However, for branched alkanes and all alkenes, the leaving ClMn+ abstracts a weakly bound hydride, an alkyl anion, or an alkene from the hydrocarbon to generate diagnostic carbocation fragment ions. Because the experiment involves isolation of the ionized analytes prior to structural characterization (MS/MS), it is well-suited for direct analysis of hydrocarbon mixtures." @default.
- W2045708534 created "2016-06-24" @default.
- W2045708534 creator A5005478397 @default.
- W2045708534 creator A5018401580 @default.
- W2045708534 creator A5039490310 @default.
- W2045708534 creator A5049631267 @default.
- W2045708534 creator A5056660920 @default.
- W2045708534 creator A5076754955 @default.
- W2045708534 date "2010-05-05" @default.
- W2045708534 modified "2023-10-12" @default.
- W2045708534 title "Differentiation of Isomeric Hydrocarbons by Using [ClMn(H<sub>2</sub>O)]<sup>+</sup> Chemical Ionization and Collision-Activated Dissociation in a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer" @default.
- W2045708534 cites W1554295456 @default.
- W2045708534 cites W1556306695 @default.
- W2045708534 cites W1967202251 @default.
- W2045708534 cites W1969421689 @default.
- W2045708534 cites W1970885336 @default.
- W2045708534 cites W1971040940 @default.
- W2045708534 cites W1973847141 @default.
- W2045708534 cites W1974182573 @default.
- W2045708534 cites W1981209426 @default.
- W2045708534 cites W1985479306 @default.
- W2045708534 cites W1989335047 @default.
- W2045708534 cites W1989454485 @default.
- W2045708534 cites W1990013044 @default.
- W2045708534 cites W1995408105 @default.
- W2045708534 cites W1996874245 @default.
- W2045708534 cites W1998829559 @default.
- W2045708534 cites W2000102716 @default.
- W2045708534 cites W2001426933 @default.
- W2045708534 cites W2002281201 @default.
- W2045708534 cites W2007856818 @default.
- W2045708534 cites W2009827129 @default.
- W2045708534 cites W2016585825 @default.
- W2045708534 cites W2020131889 @default.
- W2045708534 cites W2021194045 @default.
- W2045708534 cites W2026978122 @default.
- W2045708534 cites W2027220862 @default.
- W2045708534 cites W2028265937 @default.
- W2045708534 cites W2044243183 @default.
- W2045708534 cites W2045276866 @default.
- W2045708534 cites W2045706475 @default.
- W2045708534 cites W2052973986 @default.
- W2045708534 cites W2054727229 @default.
- W2045708534 cites W2057365035 @default.
- W2045708534 cites W2059750413 @default.
- W2045708534 cites W2061869357 @default.
- W2045708534 cites W2065256449 @default.
- W2045708534 cites W2075737410 @default.
- W2045708534 cites W2075903941 @default.
- W2045708534 cites W2081065653 @default.
- W2045708534 cites W2088078058 @default.
- W2045708534 cites W2091730145 @default.
- W2045708534 cites W2124843186 @default.
- W2045708534 cites W2139136664 @default.
- W2045708534 cites W2160705629 @default.
- W2045708534 cites W239249307 @default.
- W2045708534 cites W2921323522 @default.
- W2045708534 cites W2949419917 @default.
- W2045708534 cites W2953089120 @default.
- W2045708534 cites W3004604759 @default.
- W2045708534 cites W4241144970 @default.
- W2045708534 doi "https://doi.org/10.1021/ef100244y" @default.
- W2045708534 hasPublicationYear "2010" @default.
- W2045708534 type Work @default.
- W2045708534 sameAs 2045708534 @default.
- W2045708534 citedByCount "5" @default.
- W2045708534 countsByYear W20457085342016 @default.
- W2045708534 countsByYear W20457085342023 @default.
- W2045708534 crossrefType "journal-article" @default.
- W2045708534 hasAuthorship W2045708534A5005478397 @default.
- W2045708534 hasAuthorship W2045708534A5018401580 @default.
- W2045708534 hasAuthorship W2045708534A5039490310 @default.
- W2045708534 hasAuthorship W2045708534A5049631267 @default.
- W2045708534 hasAuthorship W2045708534A5056660920 @default.
- W2045708534 hasAuthorship W2045708534A5076754955 @default.
- W2045708534 hasConcept C102931765 @default.
- W2045708534 hasConcept C111919701 @default.
- W2045708534 hasConcept C113196181 @default.
- W2045708534 hasConcept C145148216 @default.
- W2045708534 hasConcept C147789679 @default.
- W2045708534 hasConcept C161790260 @default.
- W2045708534 hasConcept C162356407 @default.
- W2045708534 hasConcept C170552419 @default.
- W2045708534 hasConcept C176107965 @default.
- W2045708534 hasConcept C178790620 @default.
- W2045708534 hasConcept C185592680 @default.
- W2045708534 hasConcept C191015642 @default.
- W2045708534 hasConcept C193055867 @default.
- W2045708534 hasConcept C198291218 @default.
- W2045708534 hasConcept C2776254738 @default.
- W2045708534 hasConcept C2777207669 @default.
- W2045708534 hasConcept C31827203 @default.
- W2045708534 hasConcept C32909587 @default.
- W2045708534 hasConcept C39527238 @default.
- W2045708534 hasConcept C41008148 @default.
- W2045708534 hasConcept C43617362 @default.
- W2045708534 hasConcept C51884965 @default.
- W2045708534 hasConcept C75473681 @default.