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- W204570888 abstract "Abstract Carbanions containing leaving groups at the carbanionic center react with variety of nitroarenes replacing hydrogen in the o-and p-positions to the nitro group by the carbanion moiety, the substituent X acts as a vicarious leaving group. This new type of the nucleophilic substitution of hydrogen offers a general method for introduction of functionalized alkyl substituents into o-or p-positions of nitroarenes and also some aromatic heterocycles. This reaction is therefore a process complementary to the Friedel-Crafts reaction for those arenes which are resistant toward electrophilic attack. The scope, limitations, some specific features and the mechanism of this reaction as well as some of its synthetic consequences will be discussed." @default.
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- W204570888 date "1983-01-01" @default.
- W204570888 modified "2023-10-18" @default.
- W204570888 title "VICARIOUS NUCLEOPHILIC SUBSTITUTION OF HYDROGEN. A NEW METHOD OF NUCLEOPHILIC ALKYLATION OF NITROARENES" @default.
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- W204570888 doi "https://doi.org/10.1016/b978-0-08-029217-5.50038-3" @default.
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