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• W2045731966 startingPage "3058" @default.
• W2045731966 abstract "Several binuclear cobalt(III) complexes that mimic Ru-based water oxidation catalysts have been prepared. The initial complexes exhibited thermodynamic instability and kinetic lability that complicated efforts to use these cobalt complexes as electrocatalysts for water oxidation. Binuclear cobalt(III) complexes supported by a bridging bispyridylpyrazolate (bpp) ligand overcome these limitations. Two bpp-ligated dicobalt(III)-peroxo complexes were prepared and structurally characterized, and electrochemical investigation of these complexes supports their ability to serve as molecular electrocatalysts for water oxidation under acidic conditions (pH 2.1)." @default.
• W2045731966 created "2016-06-24" @default.
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• W2045731966 date "2012-01-01" @default.
• W2045731966 modified "2023-10-05" @default.
• W2045731966 title "Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution" @default.
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• W2045731966 doi "https://doi.org/10.1039/c2sc20755a" @default.
• W2045731966 hasPublicationYear "2012" @default.
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