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- W2045747297 abstract "Existing ion-chemical scheme has been applied to reproduce the positive ion composition measured on 30 June 1973 by a rocket-borne mass spectrometer flown from Wallops Island. It is found that reactions analogous to the conversion of NO+ to NO+·H2O are able to reproduce the observed densities of NO+·(H2O)2 and NO+·(H2O)3. The theoretical values of O2+ and O2+·H2O are found to be about an order of magnitude higher and lower respectively than those measured. The direct hydration rates of H+·(H2O)n ions given by Good et al (1970) yield much less hydrates for n > 2. To properly reproduce the observed positive ions we need the following: (a) a reaction which will convert O2+ to O2+·H2O in the form O with U1 = 10−31[M]2(300/T)4.4s−1 and U2 = 10−9[H2O]s−1; and (b) formation of hydrated protons via intermediate ions in the form with S=10−9[H20]s−1, F = 8 × 10−32[M]2(300/T)4.4s−1 and B increasing from 10−3 to 102S−1 as n increases from 2 to 6." @default.
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- W2045747297 date "1978-04-01" @default.
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- W2045747297 title "An attempt to identify the obscured paths of water cluster ions build-up in the D-region" @default.
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- W2045747297 doi "https://doi.org/10.1016/0021-9169(78)90175-7" @default.
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