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- W2045752570 abstract "Point defects diagrams for the Cu2±δO, both pure and doped with M2+ metal ions with all the types of defects in the cation sublattice considered are presented in this work. The calculations of the diagrams were performed by a novel method. The calculations were based on the data from the results of the studies of the deviation from stoichiometry and the electrical conductivity in the temperature range of 873–1473 K. The values of ΔGo of the formation of Frenkel-type defects, of copper vacancies, and of interstitial copper atoms were determined and their temperature dependence. It was shown that character of the dependence of the sum of concentrations of electronic defects ([h•]+b[e′]) on pO2 is fully consistent with its dependence of the electrical conductivity. Their mobility (μe/μh=b), vary from 1300 to 30. The dope M2+ increases the concentration of electrons and shifts the minimum of electrical conductivity toward higher oxygen pressures." @default.
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- W2045752570 date "1977-01-01" @default.
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- W2045752570 title "The diffusion of Cu in copper(i) oxide" @default.
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- W2045752570 doi "https://doi.org/10.1016/0022-3697(77)90050-6" @default.
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