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• W2045756565 abstract "Reaction of [Ir(cod)(py)2][PF6] with PPh3 or P(C6H4-4-F)3 gives the bis(phosphine) derivative [Ir(cod)L2][PF6], but with the poorly basic phosphine P(C6H4-4-CF3)3 or AsPh3 the mixed ligand complexes [Ir(cod)L(py)][PF6] are obtained. The synthesis of [Ir(AsPh3)(cod)(PPh3)][CF3SO3] is described, and the structures of this and of [Ir(AsPh3)(cod)(py)][PF6] determined by X-ray crystallography. The use of some of the complexes as catalysts for imine hydrogenation is described." @default.
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• W2045756565 date "1997-01-01" @default.
• W2045756565 modified "2023-09-25" @default.
• W2045756565 title "Anomalous reactivity of triphenylarsine and triarylphosphines of low basicity with [Ir(cod)(py)2][PF6] and use of the complexes as precatalysts for imine hydrogenation" @default.
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• W2045756565 doi "https://doi.org/10.1016/s0022-328x(96)06627-2" @default.
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