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• W2045768778 abstract "Polymer membranes containing α-cyclodextrin (α-CD) were prepared by the casting method using cross-linking reaction with hexamethylenediisocyanate. The film synthesis conducted with and without dibutyltin dilaurate as catalyst, resulted in two series of materials in which α-CD host entities were chemically linked to polyvinyl alcohol and physically entrapped, respectively. The obtained membranes were successfully applied to the separation of o-/p- and o-/m-xylene isomer mixtures by pertraction from water. p- and m-xylenes were found to be the faster permeants compared to the o-isomer. The separation factor of p-xylene over o-xylene varied from 7.75 to 0.35 depending on the membrane α-CD content and the feed concentration ratio. Permeation rate and separation selectivity data were discussed in terms of molecular recognition by α-CD and of coupling transport effect. Both kinds of materials showed similar behaviour in their permeation performances indicating that inclusion interaction was not changed by the chemical grafting on PVA chains." @default.
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• W2045768778 date "2005-11-01" @default.
• W2045768778 modified "2023-10-06" @default.
• W2045768778 title "Preparation and characterization of α-cyclodextrin-containing membranes—application to the selective extraction of xylene isomers" @default.
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• W2045768778 doi "https://doi.org/10.1016/j.polymer.2005.07.083" @default.
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