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- W2045773617 abstract "Compounds 5 (4,8,13,17,21-pentamethyl-4,8,12,16,20-docasapen- taenyl chloride and tosylate) were prepared starting from squalene and the solvolysis rates were measured in 80% (v/v) aqueous ethanol. a-Deuterium secondary kinetic isotope effects and activation parameters were calculated, and the products were determined. According to the values obtained (/CH/JCD — 0.99 ± 0.06, A H={= = 86.6 kJ mol1, A S+ = —69.3 J mol-1 K-1) and on the basis of isolated aliphatic products (11 and 14) it is concluded that the substrate follows the SN2 type displacement reaction with solvent without jt^participation of the double bond." @default.
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- W2045773617 date "2010-08-23" @default.
- W2045773617 modified "2023-10-11" @default.
- W2045773617 title "ChemInform Abstract: Solvolytic Behaviour of a Primary Squalene Derivative." @default.
- W2045773617 cites W3021375788 @default.
- W2045773617 doi "https://doi.org/10.1002/chin.199103079" @default.
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