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- W2045780543 abstract "The high-pressure Raman spectra of ferroelastic NaAl(MoO4)2 have been measured at room temperature. The studies indicated that this crystal exhibits two pressure-induced phase transitions at about 1.1 and 3.3 GPa. The first transition is connected with slight rotation of the MoO4−2 tetrahedra with loss of the inversion centre. The second transition is connected with significant distortion of the MoO42− tetrahedra and Al3+ coordination sphere. By performing the lattice dynamics calculations in the starting phase (monoclinic C2h6) we have been able to make an assignment of the Raman modes of this material. The deep knowledge of the modes helped us to get fundamental insights into the mechanism driving the structural changes occurring in NaAl(MoO4)2. The two phase transitions observed in the 0.0–4.2 GPa pressure range are completely reversible." @default.
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- W2045780543 date "2004-07-02" @default.
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- W2045780543 title "Raman scattering study of NaAl(MoO4)2crystal under high pressures" @default.
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- W2045780543 doi "https://doi.org/10.1088/0953-8984/16/28/033" @default.
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