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• W2045796670 abstract "Li4FeH6, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900 °C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li4FeH6 is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li4FeH6 at moderate pressures. Li4FeH6 can be recovered at ambient conditions where Li4FeH6 is metastable." @default.
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• W2045796670 date "2014-07-01" @default.
• W2045796670 modified "2023-10-03" @default.
• W2045796670 title "Li4FeH6: Iron-containing complex hydride with high gravimetric hydrogen density" @default.
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• W2045796670 doi "https://doi.org/10.1063/1.4886219" @default.
• W2045796670 hasPublicationYear "2014" @default.
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