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- W2045799051 abstract "Distribution of nicotinic acid between water and Alamine 336, a mixture of tertiary aliphatic amines, dissolved in various (proton-donating and -accepting, polar and nonpolar) diluents, as well as a comparison with the extraction equilibria of pure diluent alone have been studied at 298 K and the phase ratio of 1:1 (v/v). Cyclic alcohol/amine system yields the largest synergistic extraction efficiency. The strength of the complex solvation has been found to be reasonably high for halogenated aliphatic hydrocarbons and nitrobenzene promoting mainly the formation of acid1–amine1 structure. The influence of the acid structure over distribution has been evaluated through comparing the extractabilities of six acids containing different functional groups, i.e., benzoic, valeric, formic, levulinic, acetic and nicotinic acids. The results were correlated using various versions of the mass action law, i.e., a modified Langmuir equilibrium model and a chemodel approach comprising the formation of one or two acid–amine aggregated structures." @default.
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- W2045799051 date "2001-08-01" @default.
- W2045799051 modified "2023-10-18" @default.
- W2045799051 title "Extraction equilibria of nicotinic acid using Alamine 336 and conventional solvents: effect of diluent" @default.
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- W2045799051 doi "https://doi.org/10.1016/s1385-8947(00)00236-9" @default.
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